According to my lawyer an LLC is better because you can have different class of stock. When you are ready to negotiate the operating agreement with your angel investor you have more options. Forming a regular corporation only allows 1 class of stock putting everyone on the same playing field so to speak. With an LLC you can limit the control the investor has by selling a different class of stock.
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The "single class of stock" restriction applies to "S" corp structure. The C corp structure can have m,ultiple classes of stock as defined in the articles of incorporation.
Unless you have some special circumstances, I would suggest creating the operating agreement before engaging with investors.
It depends on what you are looking to do with your corporation. We chose on the advice of our lawyer a LLC to prevent double taxation that you can get when you sell shares of a C corp. Here is a link that compares C corp to LLC.
As a business person depending on your business plan an its exit strategy is what you should use to determine what type of corporation you need to set up.